Synthesis of hetero- and homo-multinuclear complexes with a tetracyanonickelate anion: structural characterization [Cu(bcen)Ni(CN)4]2

Synthesis of hetero- and homo-multinuclear complexes with a tetracyanonickelate anion: structural characterization [Cu(bcen)Ni(CN)4]2

Two new complexes [Cu(bcen)Ni(CN)4]2 (1) and [Ni(bcen)Ni(CN)4] (2) where bcen is 4,7-diazadecanediamide, were synthesized by reaction of equimolar amounts of M(NO3)2 (M = Cu and Ni), bcen ligand and K2[Ni(CN)4]. Single-crystal X-ray diffraction analysis of compound 1, shows that the bcen ligand acts...

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Bibliographic Details
Main Authors: Rasoul Vafazadeh, Amin Dehghani-Firouzabadi, Anthony C. Willis
Format: Article
Language:English
Published: Slovenian Chemical Society 2017-09-01
Series:Acta Chimica Slovenica
Subjects:
Cyano bridged
Multinuclear
diamine-diamide
Crystal structure
tetracyanonickelate
Online Access:https://journals.matheo.si/index.php/ACSi/article/view/3577

Internet

https://journals.matheo.si/index.php/ACSi/article/view/3577

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