Reactions of diiron m-aminocarbyne complexes containing nitrile ligands

Reactions of diiron m-aminocarbyne complexes containing nitrile ligands

The acetonitrile ligand in the mu-aminocarbyne complexes [Fe2{mu-CN(Me)R}(mu-CO)(CO)(NCMe)(Cp)2][SO 3CF3] (R = Me, 2a, CH2Ph, 2b, Xyl, 2c) (Xyl = 2,6-Me2C6H3) is readily displaced by halides and cyanide anions affording the corresponding neutral species [Fe2{mu-CN(Me)R}(mu-CO)(CO)(X)(Cp)2 ] (X = Br,...

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Bibliographic Details
Main Authors: Busetto Luigi, Marchetti Fabio, Zacchini Stefano, Zanotti Valerio
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2003-01-01
Series:Journal of the Brazilian Chemical Society
Subjects:
acetonitrile
nitrile activation
carbyne complexes
dinuclear complexes
C-C bond formation
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000600006

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http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000600006

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