Synthesis of Ruthenium(III) Phthalocyanine with Di-axial Bromo Ligands - A Promising Molecular Conductor with Giant Negative Magnetoresistance

The electron transport of Phthalocyanines (Pc) with central metal and di-axial ligands (such as FeIII(Pc)L2; where L = CN, Cl, Br) originates from its intermolecular Pc π-π orbital overlap while its giant negative magnetoresistance (GNMR) arises from its intramolecular Pc-π(HOMO) and Fe-d (s=1/2) in...

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Bibliographic Details
Main Authors: Mario A.V. Gamboa, Joey A.A. Valinton, Derrick E.C. Yu
Format: Article
Language:English
Published: Growing Science 2015-01-01
Series:Current Chemistry Letters
Subjects:
Online Access:http://www.growingscience.com/ccl/Vol4/ccl_2014_23.pdf