Synthesis of Ruthenium(III) Phthalocyanine with Di-axial Bromo Ligands - A Promising Molecular Conductor with Giant Negative Magnetoresistance
The electron transport of Phthalocyanines (Pc) with central metal and di-axial ligands (such as FeIII(Pc)L2; where L = CN, Cl, Br) originates from its intermolecular Pc π-π orbital overlap while its giant negative magnetoresistance (GNMR) arises from its intramolecular Pc-π(HOMO) and Fe-d (s=1/2) in...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Growing Science
2015-01-01
|
| Series: | Current Chemistry Letters |
| Subjects: | |
| Online Access: | http://www.growingscience.com/ccl/Vol4/ccl_2014_23.pdf |