Synthesis of Ethylene or Propylene/1,3-Butadiene Copolymers Possessing Pendant Vinyl Groups with Virtually No Internal Olefins

Synthesis of Ethylene or Propylene/1,3-Butadiene Copolymers Possessing Pendant Vinyl Groups with Virtually No Internal Olefins

In general, ethylene/1,3-butadiene copolymerizations provides copolymers possessing both pendant vinyls and vinylenes as olefinic moieties. We, at MCI, studied the substituent effects of C2-symmetric zirconocene complexes, rac-[Me2Si(Indenyl’)2]ZrCl2 (Indenyl’ = generic substituted indenyl), after a...

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Bibliographic Details
Main Authors: Kenji Michiue, Makoto Mitani, Terunori Fujita
Format: Article
Language:English
Published: MDPI AG 2015-11-01
Series:Catalysts
Subjects:
1,3-butadiene
C2-symmetric zirconocene
insertion mode
vinyl groups
internal olefins
vinylenes
Online Access:http://www.mdpi.com/2073-4344/5/4/2001

Internet

http://www.mdpi.com/2073-4344/5/4/2001

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