Formation of sulfido ciobium complexes through C-S bond activation
Upon reacting (eta5-C5H5)2NbCl2, eta5-C5H5 = Cp, and (Ph)3Sn(SPh), in THF, (eta5-C5H5)2Nb(Cl)(mu-S)Sn(Ph)3(Cl), 1, and (eta5-C5H5)2Nb(S)Cl, 2, were obtained. Complexes 1 and 2 were characterized by IR, ¹H-NMR, 13C-NMR, Mössbauer spectroscopies, elemental analysis as well as by atomic absorption. Hyd...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Sociedade Brasileira de Química
1998-01-01
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| Series: | Journal of the Brazilian Chemical Society |
| Subjects: | |
| Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000300012 |