Exceptional uranium(VI)-nitride triple bond covalency from 15N nuclear magnetic resonance spectroscopy and quantum chemical analysis

Exceptional uranium(VI)-nitride triple bond covalency from 15N nuclear magnetic resonance spectroscopy and quantum chemical analysis

Determining the covalency of actinide chemical bonding is a fundamentally important challenge. Here, the authors report a 15N nuclear magnetic resonance spectroscopy study of a terminal uranium-nitride, revealing exceptional NMR properties and covalency that redefine 15N NMR parameter space and acti...

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Bibliographic Details
Main Authors: Jingzhen Du, John A. Seed, Victoria E. J. Berryman, Nikolas Kaltsoyannis, Ralph W. Adams, Daniel Lee, Stephen T. Liddle
Format: Article
Language:English
Published: Nature Publishing Group 2021-09-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-021-25863-2

Internet

https://doi.org/10.1038/s41467-021-25863-2

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