Effect of Transition Metal Substitution on the Structure and Properties of a Clathrate-Like Compound Eu7Cu44As23

Effect of Transition Metal Substitution on the Structure and Properties of a Clathrate-Like Compound Eu7Cu44As23

A series of substitutional solid solutions—Eu7Cu44−xTxAs23 (T = Fe, Co, Ni)—based on a recently discovered clathrate-like compound (Eu7Cu44As23) were synthesized from the elements at 800 °C. Almost up to 50% of Cu can be substituted by Ni, resulting in a linear decrease of the cubic unit cell parame...

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Bibliographic Details
Main Authors: Igor V. Plokhikh, Dmitri O. Charkin, Valeriy Yu. Verchenko, Ivan A. Ignatyev, Sergey M. Kazakov, Alexey V. Sobolev, Igor A. Presniakov, Alexander A. Tsirlin, Andrei V. Shevelkov
Format: Article
Language:English
Published: MDPI AG 2016-07-01
Series:Materials
Subjects:
clathrate
synthesis
crystal structure
magnetic properties
energy production
conversion
storage
Online Access:http://www.mdpi.com/1996-1944/9/7/587

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http://www.mdpi.com/1996-1944/9/7/587

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