Why Is Water More Reactive Than Hydrogen in Photocatalytic CO2 Conversion at Higher Pressures? Elucidation by Means of X-Ray Absorption Fine Structure and Gas Chromatography–Mass Spectrometry
Photocatalytic conversion of CO2 into mainly methane using Pd/TiO2 photocatalyst proceeded faster at 0.80 MPa using water rather than hydrogen as a reductant. The former reaction (CO2 + water) consists of two steps: first, water photosplitting and second, the latter reaction (CO2 + hydrogen). It was...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Frontiers Media S.A.
2018-09-01
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| Series: | Frontiers in Chemistry |
| Subjects: | |
| Online Access: | https://www.frontiersin.org/article/10.3389/fchem.2018.00408/full |