Carbon–carbon bond cleavage for Cu-mediated aromatic trifluoromethylations and pentafluoroethylations

Carbon–carbon bond cleavage for Cu-mediated aromatic trifluoromethylations and pentafluoroethylations

This short review highlights the copper-mediated fluoroalkylation using perfluoroalkylated carboxylic acid derivatives. Carbon–carbon bond cleavage of perfluoroalkylated carboxylic acid derivatives takes place in fluoroalkylation reactions at high temperature (150–200 °C) or under basic conditions t...

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Bibliographic Details
Main Authors: Tsuyuka Sugiishi, Hideki Amii, Kohsuke Aikawa, Koichi Mikami
Format: Article
Language:English
Published: Beilstein-Institut 2015-12-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
β-carbon elimination
carbon–carbon bond cleavage
decarboxylation
tetrahedral intermediate
trifluoroacetate
fluoral
trifluoromethylation
Online Access:https://doi.org/10.3762/bjoc.11.286

Internet

https://doi.org/10.3762/bjoc.11.286

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