Chiral trimethylsilylated C2-symmetrical diamines as phosphorous derivatizing agents for the determination of the enantiomeric excess of chiral alcohols by 1H NMR

The use of organophosphorus derivatising agents, prepared from C2 symmetric trimethylsilylated diamines, for the 1H NMR and 31P NMR determination of the enantiomeric composition of chiral alcohols is described.

Bibliographic Details
Main Authors: Anne-Sophie Chauvin, Alexandre Alexakis
Format: Article
Language:English
Published: Beilstein-Institut 2006-03-01
Series:Beilstein Journal of Organic Chemistry
Online Access:https://doi.org/10.1186/1860-5397-2-6