The Role of Coulomb Interactions for Spin Crossover Behaviors and Crystal Structural Transformation in Novel Anionic Fe(III) Complexes from a π-Extended ONO Ligand

The Role of Coulomb Interactions for Spin Crossover Behaviors and Crystal Structural Transformation in Novel Anionic Fe(III) Complexes from a π-Extended ONO Ligand

To investigate the π-extension effect on an unusual negative-charged spin crossover (SCO) FeIII complex with a weak N2O4 first coordination sphere, we designed and synthesized a series of anionic FeIII complexes from a π-extended naphthalene derivative ligand. Acetonitrile-solvate tetramethylammoniu...

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Bibliographic Details
Main Authors: Suguru Murata, Kazuyuki Takahashi, Takahiro Sakurai, Hitoshi Ohta, Takashi Yamamoto, Yasuaki Einaga, Yoshihito Shiota, Kazunari Yoshizawa
Format: Article
Language:English
Published: MDPI AG 2016-05-01
Series:Crystals
Subjects:
spin crossover
Coulomb interaction
π-stacking interaction
crystal structural transformation
mononuclear Fe(III) complex
anionic complex
ONO tridentate ligand
Online Access:http://www.mdpi.com/2073-4352/6/5/49

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http://www.mdpi.com/2073-4352/6/5/49

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