ETHYLENE POLYMERIZATION WITH NICKEL DIIMINE COMPLEXES CONTAINING PSEUDOHALIDES

ETHYLENE POLYMERIZATION WITH NICKEL DIIMINE COMPLEXES CONTAINING PSEUDOHALIDES

Nickel-diimine complexes DADNiX2 (DAD= 2,6-iPr2-C6H3-N=C(Me)-C(Me)=N-2,6-iPr2-C6H3) containing the non-chelating pseudo-halide ligands isothyocyanate and isoseleniumcyanate (X= NCS 1 and NCSe 2) were synthesized and used in ethylene polymerization activated by methyaluminoxane (MAO) at temperatures...

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Bibliographic Details
Main Authors: Marcos L. Dias, Luciana P. Silva, Geraldo L. Crossetti, Carlos A. L. Filgueiras
Format: Article
Language:English
Published: Sociedade Brasileira de Química
Series:Química Nova
Subjects:
ethylene polymerization
pseudo-halide ligands
Ni-diimine complexes
isothiocyanate
isoseleniumcyanate
branched polyethylenes
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422018000700719&lng=en&tlng=en

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http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422018000700719&lng=en&tlng=en

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