Facial synthesis of sulfinic esters via copper-catalyzed reaction of sulfonyl hydrazides with alcohols in air

The efficient Cu-catalyzed esterification of sulfonyl hydrazides with alcohols in air is described, providing sulfinic esters in good yields and broad scope. Mechanistic studies suggest that the reaction likely proceeds through free-radical formation including arylthio radical and arylsulfonyl radic...

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Bibliographic Details
Main Authors: Lingjuan Chen, Jiangxin Pu, Ping Liu, Bin Dai
Format: Article
Language:English
Published: Elsevier 2019-12-01
Series:Journal of Saudi Chemical Society
Online Access:http://www.sciencedirect.com/science/article/pii/S1319610319300730