Versatile deprotonated NHC: C,N-bridged dinuclear iridium and rhodium complexes

Versatile deprotonated NHC: C,N-bridged dinuclear iridium and rhodium complexes

Bearing the versatility of N-heterocyclic carbene (NHC) ligands, here density functional theory (DFT) calculations unravel the capacity of coordination of a deprotonated NHC ligand (pNHC) to generate a doubly C2,N3-bridged dinuclear complex. Here, in particular the discussion is based on the combina...

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Bibliographic Details
Main Author: Albert Poater
Format: Article
Language:English
Published: Beilstein-Institut 2016-01-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
DFT
head-to-head
head-to-tail
iridium
isomerization
N-heterocyclic carbene
rhodium
Online Access:https://doi.org/10.3762/bjoc.12.13

Internet

https://doi.org/10.3762/bjoc.12.13

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