The Reaction of Trimethylsilylethynyl(phenyl)iodonium Triflate with Some Phenolates: Formation of Substitution and sp2 C-H Insertion Products

Treatment of trimethylsilylethynyl(phenyl)iodonium triflate with the potassium salts of some acidic phenols results in the formation of substitution products (O-trimethylsilylethynylphenols and/or O-ethynylphenols), along with sp2C-H insertion products which afford eventually 2-aroxybenzo[b]furans.

Bibliographic Details
Main Authors: Anastasios Varvoglis, Nestor Rodios, Spyros Nikas
Format: Article
Language:English
Published: MDPI AG 2000-11-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/5/11/1182/