Synthesis and Structure of a Sodium Complex of an Aromatic β-Diketone and Pyrazolylpyridine

Synthesis and Structure of a Sodium Complex of an Aromatic β-Diketone and Pyrazolylpyridine

Reaction of NaH with a THF solution of Eu(BTA)3(pypzH) [BTA = 1-benzoyl-3,3,3-trifluoroacetonate, pypzH = 2-(3-pyrazolyl)pyridine] leads to the formation of theeuropium-free tetrasodium complex [Na4(pypzH)2(μ4-BTA)2(μ2-BTA)2]. Single-crystal X-ray diffraction studies revealed the presence of a...

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Bibliographic Details
Main Authors: Isabel S. Gonçalves, Martyn Pillinger, Jacek Klinowski, Filipe A. Almeida Paz, Ana C. Coelho
Format: Article
Language:English
Published: MDPI AG 2006-07-01
Series:Molecules
Subjects:
Sodium
bridging ligands
N ligands
O ligands
coordination modes
aggregation
Online Access:http://www.mdpi.com/1420-3049/11/7/528/

Internet

http://www.mdpi.com/1420-3049/11/7/528/

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