Dehydration Process of Hofmann-Type Layered Solids

In the present work the dehydration process of layered solids with formula unit M(H2O)2[Ni(CN)4]·nH2O, M = Ni, Co, Mn; n = 1, 2, 4 is studied using modulated thermogravimetry. The results show that water molecules need to overcome an energetic barrier (activation energy between 63 and 500 kJ/mol) in...

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Bibliographic Details
Main Authors: Edilso Reguera, Enelio Torres-García, Geonel Rodríguez-Gattorno, Omar Reyes-Martinez
Format: Article
Language:English
Published: MDPI AG 2013-04-01
Series:Materials
Subjects:
Online Access:http://www.mdpi.com/1996-1944/6/4/1452