Formation of 1-aza-2-silacyclopentanes and unexpected products from the insertion of phenylisocyanate into 2,2-dimethyl-1-(trimethylsilyl)-1-aza-2-silacyclopentane

Substances like 3-aminopropyltriethoxysilane are often used as adhesive promoters in various formulations for coatings or to adjust the properties of siloxanes and other polymers. Cyclisation of similar substances is also interesting because of the formation of the Si-N bond. 1-Aza-2-silacyclopentan...

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Bibliographic Details
Main Authors: Herbig Marcus, Böhme Uwe, Schwarzer Anke, Kroke Edwin
Format: Article
Language:English
Published: De Gruyter 2018-05-01
Series:Main Group Metal Chemistry
Subjects:
Online Access:https://doi.org/10.1515/mgmc-2018-0005