Crystal structure of (η4-cyclooctadiene)(3,3′-dimesityl-1,1′-methylenediimidazoline-2,2′-diylidene)nickel(0) tetrahydrofuran monosolvate

Crystal structure of (η4-cyclooctadiene)(3,3′-dimesityl-1,1′-methylenediimidazoline-2,2′-diylidene)nickel(0) tetrahydrofuran monosolvate

The crystal structure of the title compound, [Ni(C25H28N4)(C8H12)]·C4H8O or (MesNHC2Me)Ni(COD), which contains a bidentate N-heterocyclic carbene (NHC) ligand with mesityl aryl groups is reported. The complex at 100 K has monoclinic (P21/c) symmetry and a distorted tetrahedral geometry around the ni...

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Bibliographic Details
Main Authors: Carlos D. Yamamoto, Zijie Zhang, Sabine Chantal E. Stieber
Format: Article
Language:English
Published: International Union of Crystallography 2018-10-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
inorganic chemistry
organometallic chemistry
NHC
nickel
carbene
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018012252

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http://scripts.iucr.org/cgi-bin/paper?S2056989018012252

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