A New Electrically Conducting Metal–Organic Framework Featuring U-Shaped cis-Dipyridyl Tetrathiafulvalene Ligands

A New Electrically Conducting Metal–Organic Framework Featuring U-Shaped cis-Dipyridyl Tetrathiafulvalene Ligands

A new electrically conducting 3D metal-organic framework (MOF) with a unique architecture was synthesized using 1,2,4,5-tetrakis-(4-carboxyphenyl)benzene (TCPB) a redox-active cis-dipyridyl-tetrathiafulvalene (Z-DPTTF) ligand. While TCPB formed Zn2(COO)4 secondary building units (SBUs), instead of c...

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Bibliographic Details
Main Authors: Monica A. Gordillo, Paola A. Benavides, Kaybriana Spalding, Sourav Saha
Format: Article
Language:English
Published: Frontiers Media S.A. 2021-10-01
Series:Frontiers in Chemistry
Subjects:
metal-organic frameworks
redox-active
tetrathiafulvalene
electrical conductivity
iodine
Online Access:https://www.frontiersin.org/articles/10.3389/fchem.2021.726544/full

Internet

https://www.frontiersin.org/articles/10.3389/fchem.2021.726544/full

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