Ultralong π-Conjugated Bis(terpyridine)metal Polymer Wires Covalently Bound to a Carbon Electrode: Fast Redox Conduction and Redox Diode Characteristics

Ultralong π-Conjugated Bis(terpyridine)metal Polymer Wires Covalently Bound to a Carbon Electrode: Fast Redox Conduction and Redox Diode Characteristics

We developed an efficient and convenient electrochemical method to synthesize π-conjugated redox metal-complex linear polymer wires composed of azobenzene-bridged bis(terpyridine)metal (<b>2-M</b>, M = Fe, Ru) units covalently immobilized on glassy carbon (GC). Polymerization proceeds by...

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Bibliographic Details
Main Authors: Kuo-Hui Wu, Ryota Sakamoto, Hiroaki Maeda, Eunice Jia Han Phua, Hiroshi Nishihara
Format: Article
Language:English
Published: MDPI AG 2021-07-01
Series:Molecules
Subjects:
electropolymerization
coordination polymer
electron transfer
modified electrode
redox
hetero-metal complex
Online Access:https://www.mdpi.com/1420-3049/26/14/4267

Internet

https://www.mdpi.com/1420-3049/26/14/4267

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