Crystal structure of bis{μ2-2,2′-[(4,10-dimethyl-1,4,7,10-tetraazacyclododecane-1,7-diyl)bis(methylene)]bis(4-oxo-4H-pyran-3-olato)}dicobaltcalcium bis(perchlorate) 1.36-hydrate

Crystal structure of bis{μ2-2,2′-[(4,10-dimethyl-1,4,7,10-tetraazacyclododecane-1,7-diyl)bis(methylene)]bis(4-oxo-4H-pyran-3-olato)}dicobaltcalcium bis(perchlorate) 1.36-hydrate

The title compound, [CaCo2(C22H30N4O6)2](ClO4)2·1.36H2O or {Ca[Co(H–2L1)]2}·2ClO4·1.36H2O {where L1 is 4,10-bis[(3-hydroxy-4-pyron-2-yl)methyl]-1,7-dimethyl-1,4,7,10-tetraazacyclododecane}, is a trinuclear complex whose asymmetric unit comprises a quarter of the {Ca[Co(H–2L1)]2}2+ trinuclear complex...

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Bibliographic Details
Main Authors: Patrizia Rossi, Eleonora Macedi, Paola Paoli, Luca Giorgi, Mauro Formica, Vieri Fusi
Format: Article
Language:English
Published: International Union of Crystallography 2017-12-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
macrocycle
polyamine ligands
heterotrinuclear complexes
alkaline-earth cations
maltol
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989017016693

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http://scripts.iucr.org/cgi-bin/paper?S2056989017016693

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