Stereoselective synthesis of carbohydrate-based fused bicyclic d-lactones

We describe in the present work the synthesis of carbohydrate-based chiral delta-lactones by regio- and stereoselective radical cyclization reactions. The configuration of the newly stereogenic center was found to depend on the structure of the carbohydrate moiety.

Bibliographic Details
Main Authors: Oliveira Renata B. de, Alves Ricardo J., Souza Filho José Dias de, Prado Maria Auxiliadora F.
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2003-01-01
Series:Journal of the Brazilian Chemical Society
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000300017