Detailed balance in micro- and macrokinetics and micro-distinguishability of macro-processes

We develop a general framework for the discussion of detailed balance and analyse its microscopic background. We find that there should be two additions to the well-known T- or PT-invariance of the microscopic laws of motion: 1. Equilibrium should not spontaneously break the relevant T- or PT-symme...

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Bibliographic Details
Main Author: A.N. Gorban
Format: Article
Language:English
Published: Elsevier 2014-01-01
Series:Results in Physics
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2211379714000485