Lithium and potassium aminoalkoxides

The structures of the Group 1 metal aminoalkoxides Li[OCH(CH2CNMe2)2] (1) and K[OCH(CH2CNMe2)2]∙HOCH(CH2CNMe2)2 (2) have been determined. 1 is a hexa­meric drum in which two Li3O3 rings are joined co-facially, whereas 2 is tetrameric and adopts a K4O4 ladder structure, novel for homoleptic potassium...

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Bibliographic Details
Main Authors: Cosham Samuel D., Johnson Andrew L., Jordan Laura, Mahon Mary F., Molloy Kieran C.
Format: Article
Language:English
Published: De Gruyter 2012-12-01
Series:Main Group Metal Chemistry
Subjects:
Online Access:https://doi.org/10.1515/mgmc-2012-0050