The [3+2] Annulation of CF3-Ketimines by Re Catalysis: Access to CF3-Containing Amino Heterocycles and Polyamides

The [3+2] Annulation of CF3-Ketimines by Re Catalysis: Access to CF3-Containing Amino Heterocycles and Polyamides

Summary: Transition metal catalyzed [3 + 2] annulation of imines with double bonds via directed C-H activation offers a direct access to amino cyclic motifs. However, owing to weak coordination and steric hindrance, trifluoromethylated ketimines have been an unaddressed challenge for TM-catalyzed an...

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Bibliographic Details
Main Authors: Saisai Zhang, Xun-Yong Liu, Zhenbang Chang, Xinxin Qiao, Heng-Ying Xiong, Guangwu Zhang
Format: Article
Language:English
Published: Elsevier 2020-11-01
Series:iScience
Subjects:
Chemistry
Molecular Inorganic Chemistry
Catalysis
Organic Synthesis
Online Access:http://www.sciencedirect.com/science/article/pii/S258900422030897X

Internet

http://www.sciencedirect.com/science/article/pii/S258900422030897X

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