Selective hydrosilylation of allyl chloride with trichlorosilane
Hydrosilylation of allyl chloride with trichlorosilane is industrially important but often proceeds unselectively. Here a Rh(I) catalyst which achieves 99% selectivity on gram scale is described, based on bidentate phosphine ligands.
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Publishing Group
2021-05-01
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| Series: | Communications Chemistry |
| Online Access: | https://doi.org/10.1038/s42004-021-00502-5 |