A one-dimensional iodido-bridged PtII/PtIV mixed-valence complex cation with a hydrogen sulfate counter-anion

A one-dimensional iodido-bridged PtII/PtIV mixed-valence complex cation with a hydrogen sulfate counter-anion

The title compound, catena-poly[[[bis(ethylenediamine-κ2N,N′)platinum(II)]-μ-iodido-[bis(ethylenediamine-κ2N,N′)platinum(IV)]-μ-iodido] tetra(hydrogen sulfate) dihydrate], {[PtII(C2H8N2)2][PtIVI2(C2H8N2)2](HSO4)4·2H2O}n, has a linear chain structure comprising alternating platinum cations with mixed...

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Bibliographic Details
Main Author: Nobuyuki Matsushita
Format: Article
Language:English
Published: International Union of Crystallography 2018-12-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
platinum complex
one-dimensional chain complex
iodido-bridged complex
Pt(II,IV) mixed-valence
MX-chain
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018016158

Internet

http://scripts.iucr.org/cgi-bin/paper?S2056989018016158

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