Crystal structure of a heterometallic coordination polymer: catena-poly[[[tetraaquacobalt(II)]-μ-pyridine-2,6-dicarboxylato-calcium(II)-μ-pyridine-2,6-dicarboxylato] dihydrate]

Crystal structure of a heterometallic coordination polymer: catena-poly[[[tetraaquacobalt(II)]-μ-pyridine-2,6-dicarboxylato-calcium(II)-μ-pyridine-2,6-dicarboxylato] dihydrate]

In the crystal of the title polymeric complex, {[CoCa(C7H3NO4)2(H2O)4]·2H2O}n (1), the CoII ion is N,O,O′-chelated by two pyridine-2,6-dicarboxylate anions in a distorted N2O4 octahedral geometry, and two carboxylate O atoms of pyridine-2,6-dicarboxylate anions bridge tetraaquacalcium(II) units to f...

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Bibliographic Details
Main Authors: Jie-Shuang Lin, Bing-Guang Zhang
Format: Article
Language:English
Published: International Union of Crystallography 2018-06-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
heterometallic complex
cobalt carboxylates
calcium carboxylates
pyridine-2,6-dicarboxylate anions
hydrogen bonds
offset π–π interactions
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018007120

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http://scripts.iucr.org/cgi-bin/paper?S2056989018007120

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