Four Novel Zn (II) Coordination Polymers Based on 4′-Ferrocenyl-3,2′:6′,3′′-Terpyridine: Engineering a Switch from 1D Helical Polymer Chain to 2D Network by Coordination Anion Modulation

Four Novel Zn (II) Coordination Polymers Based on 4′-Ferrocenyl-3,2′:6′,3′′-Terpyridine: Engineering a Switch from 1D Helical Polymer Chain to 2D Network by Coordination Anion Modulation

Four novel ZnII coordination polymers, [(ZnCl2)2(L)2]n (1), [(ZnBr2)2(L)2]n (2), and [(ZnI2)2(L)2]n (3) and {[Zn(SCN)2]1.5(L)3}n (4), have been synthesized based on 4′-ferrocenyl-3,2′:6′,3′′-terpyridine with ZnII ions and different coordination anions under similar ambient conditions. Their structur...

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Bibliographic Details
Main Authors: Lufei Xiao, Dajun Wu, Xuchun Wang, Wei Du, Jun Zhang, Shengli Li, Hongping Zhou, Jieying Wu, Yupeng Tian
Format: Article
Language:English
Published: MDPI AG 2017-11-01
Series:Materials
Subjects:
coordination polymer
3,2′:6′,3′′-terpyridine
ZnII ion
crystal structure
coordination anion
Online Access:https://www.mdpi.com/1996-1944/10/12/1360

Internet

https://www.mdpi.com/1996-1944/10/12/1360

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