Luminescent Polynuclear Zn- and Cd-Ln Square-Like Nanoclusters With a Flexible Long-Chain Schiff Base Ligand

Luminescent Polynuclear Zn- and Cd-Ln Square-Like Nanoclusters With a Flexible Long-Chain Schiff Base Ligand

Two series of Zn-Ln and Cd-Ln nanoclusters [Ln4Zn8L2(OAc)20(OH)4] [Ln = Nd (1), Yb (2), and Sm (3)] and [Ln2Cd2L2(OAc)2(OH)2(OCH3)2] [Ln = Nd (4), Yb (5), and Sm (6)] were prepared using a long-chain Schiff base ligand with a flexible (CH2)2O(CH2)2O(CH2)2 chain. All these clusters show square-like s...

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Bibliographic Details
Main Authors: Ting Zhu, Xiaoping Yang, Xiaohui Zheng, Shiqing Wang, Le Bo, Chengri Wang, Hongfen Chen, Dongmei Jiang, Desmond Schipper
Format: Article
Language:English
Published: Frontiers Media S.A. 2018-07-01
Series:Frontiers in Chemistry
Subjects:
self-assembly
lanthanide
flexible long-chain schiff base ligand
nanoclusters
visible and NIR luminescent
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2018.00321/full

Internet

https://www.frontiersin.org/article/10.3389/fchem.2018.00321/full

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