Enhancement of Photorefraction in Vanadium-Doped Lithium Niobate through Iron and Zirconium Co-Doping

A series of mono-, double-, and tri-doped LiNbO<sub>3</sub> crystals with vanadium were grown by Czochralski method, and their photorefractive properties were investigated. The response time for 0.1 mol% vanadium, 4.0 mol% zirconium, and 0.03 wt.% iron co-doped lithium niobate crystal at...

Full description

Bibliographic Details
Main Authors: Shahzad Saeed, Hongde Liu, Liyun Xue, Dahuai Zheng, Shiguo Liu, Shaolin Chen, Yongfa Kong, Romano Rupp, Jingjun Xu
Format: Article
Language:English
Published: MDPI AG 2019-09-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/12/19/3143
id doaj-2967d30c7b854b9eb5acf35bcdf496a4
record_format Article
spelling doaj-2967d30c7b854b9eb5acf35bcdf496a42020-11-25T02:22:58ZengMDPI AGMaterials1996-19442019-09-011219314310.3390/ma12193143ma12193143Enhancement of Photorefraction in Vanadium-Doped Lithium Niobate through Iron and Zirconium Co-DopingShahzad Saeed0Hongde Liu1Liyun Xue2Dahuai Zheng3Shiguo Liu4Shaolin Chen5Yongfa Kong6Romano Rupp7Jingjun Xu8The MOE Key Laboratory of Weak-Light Nonlinear Photonics, School of Physics and TEDA Institute of Applied Physics, Nankai University, Tianjin 300071, ChinaThe MOE Key Laboratory of Weak-Light Nonlinear Photonics, School of Physics and TEDA Institute of Applied Physics, Nankai University, Tianjin 300071, ChinaThe MOE Key Laboratory of Weak-Light Nonlinear Photonics, School of Physics and TEDA Institute of Applied Physics, Nankai University, Tianjin 300071, ChinaThe MOE Key Laboratory of Weak-Light Nonlinear Photonics, School of Physics and TEDA Institute of Applied Physics, Nankai University, Tianjin 300071, ChinaThe MOE Key Laboratory of Weak-Light Nonlinear Photonics, School of Physics and TEDA Institute of Applied Physics, Nankai University, Tianjin 300071, ChinaThe MOE Key Laboratory of Weak-Light Nonlinear Photonics, School of Physics and TEDA Institute of Applied Physics, Nankai University, Tianjin 300071, ChinaThe MOE Key Laboratory of Weak-Light Nonlinear Photonics, School of Physics and TEDA Institute of Applied Physics, Nankai University, Tianjin 300071, ChinaFaculty of Physics, Vienna University, A-1090 Wien, AustriaThe MOE Key Laboratory of Weak-Light Nonlinear Photonics, School of Physics and TEDA Institute of Applied Physics, Nankai University, Tianjin 300071, ChinaA series of mono-, double-, and tri-doped LiNbO<sub>3</sub> crystals with vanadium were grown by Czochralski method, and their photorefractive properties were investigated. The response time for 0.1 mol% vanadium, 4.0 mol% zirconium, and 0.03 wt.% iron co-doped lithium niobate crystal at 488 nm was shortened to 0.53 s, which is three orders of magnitude shorter than the mono-iron-doped lithium niobate, with a maintained high diffraction efficiency of 57% and an excellent sensitivity of 9.2 cm/J. The Ultraviolet-visible (UV-Vis) and OH<sup>&#8722;</sup> absorption spectra were studied for all crystals tested. The defect structure is discussed, and a defect energy level diagram is proposed. The results show that vanadium, zirconium, and iron co-doped lithium niobate crystals with fast response and a moderately large diffraction efficiency can become another good candidate material for 3D-holographic storage and dynamic holography applications.https://www.mdpi.com/1996-1944/12/19/3143lithium niobatephotorefractive propertiesoptical storage materialsvanadiumzirconium and iron co-doped
collection DOAJ
language English
format Article
sources DOAJ
author Shahzad Saeed
Hongde Liu
Liyun Xue
Dahuai Zheng
Shiguo Liu
Shaolin Chen
Yongfa Kong
Romano Rupp
Jingjun Xu
spellingShingle Shahzad Saeed
Hongde Liu
Liyun Xue
Dahuai Zheng
Shiguo Liu
Shaolin Chen
Yongfa Kong
Romano Rupp
Jingjun Xu
Enhancement of Photorefraction in Vanadium-Doped Lithium Niobate through Iron and Zirconium Co-Doping
Materials
lithium niobate
photorefractive properties
optical storage materials
vanadium
zirconium and iron co-doped
author_facet Shahzad Saeed
Hongde Liu
Liyun Xue
Dahuai Zheng
Shiguo Liu
Shaolin Chen
Yongfa Kong
Romano Rupp
Jingjun Xu
author_sort Shahzad Saeed
title Enhancement of Photorefraction in Vanadium-Doped Lithium Niobate through Iron and Zirconium Co-Doping
title_short Enhancement of Photorefraction in Vanadium-Doped Lithium Niobate through Iron and Zirconium Co-Doping
title_full Enhancement of Photorefraction in Vanadium-Doped Lithium Niobate through Iron and Zirconium Co-Doping
title_fullStr Enhancement of Photorefraction in Vanadium-Doped Lithium Niobate through Iron and Zirconium Co-Doping
title_full_unstemmed Enhancement of Photorefraction in Vanadium-Doped Lithium Niobate through Iron and Zirconium Co-Doping
title_sort enhancement of photorefraction in vanadium-doped lithium niobate through iron and zirconium co-doping
publisher MDPI AG
series Materials
issn 1996-1944
publishDate 2019-09-01
description A series of mono-, double-, and tri-doped LiNbO<sub>3</sub> crystals with vanadium were grown by Czochralski method, and their photorefractive properties were investigated. The response time for 0.1 mol% vanadium, 4.0 mol% zirconium, and 0.03 wt.% iron co-doped lithium niobate crystal at 488 nm was shortened to 0.53 s, which is three orders of magnitude shorter than the mono-iron-doped lithium niobate, with a maintained high diffraction efficiency of 57% and an excellent sensitivity of 9.2 cm/J. The Ultraviolet-visible (UV-Vis) and OH<sup>&#8722;</sup> absorption spectra were studied for all crystals tested. The defect structure is discussed, and a defect energy level diagram is proposed. The results show that vanadium, zirconium, and iron co-doped lithium niobate crystals with fast response and a moderately large diffraction efficiency can become another good candidate material for 3D-holographic storage and dynamic holography applications.
topic lithium niobate
photorefractive properties
optical storage materials
vanadium
zirconium and iron co-doped
url https://www.mdpi.com/1996-1944/12/19/3143
work_keys_str_mv AT shahzadsaeed enhancementofphotorefractioninvanadiumdopedlithiumniobatethroughironandzirconiumcodoping
AT hongdeliu enhancementofphotorefractioninvanadiumdopedlithiumniobatethroughironandzirconiumcodoping
AT liyunxue enhancementofphotorefractioninvanadiumdopedlithiumniobatethroughironandzirconiumcodoping
AT dahuaizheng enhancementofphotorefractioninvanadiumdopedlithiumniobatethroughironandzirconiumcodoping
AT shiguoliu enhancementofphotorefractioninvanadiumdopedlithiumniobatethroughironandzirconiumcodoping
AT shaolinchen enhancementofphotorefractioninvanadiumdopedlithiumniobatethroughironandzirconiumcodoping
AT yongfakong enhancementofphotorefractioninvanadiumdopedlithiumniobatethroughironandzirconiumcodoping
AT romanorupp enhancementofphotorefractioninvanadiumdopedlithiumniobatethroughironandzirconiumcodoping
AT jingjunxu enhancementofphotorefractioninvanadiumdopedlithiumniobatethroughironandzirconiumcodoping
_version_ 1724860737380155392