Gold coordination during homogeneous alkyne and allene cyclisation catalysis: Coordination to substrates, to ancillary ligands and in intermediates

The ever-increasing role of homogeneous gold catalysis in organic synthesis and the consequent need to be able to rationally control the rate and outcome of such reactions has emphasised the importance of each successive metal - carbon coordination step. Concentrating on alkyne and allene cyclisatio...

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Bibliographic Details
Main Authors: Helgard Raubenheimer, Hubert Schmidbaur
Format: Article
Language:English
Published: Academy of Science of South Africa 2011-03-01
Series:South African Journal of Science
Subjects:
Online Access:http://192.168.0.118/index.php/sajs/article/view/9862