Synthesis and ring openings of cinnamate-derived N-unfunctionalised aziridines
tert-Butyl cinnamates are aziridinated with high trans-selectivity by an N–N ylide generated in situ from N-methylmorpholine and O-diphenylphosphinyl hydroxylamine. The resulting N-unfunctionalised aziridines are shown to be versatile synthetic building blocks that undergo highly selective ring-open...
Main Authors: | , |
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Format: | Article |
Language: | English |
Published: |
Beilstein-Institut
2012-10-01
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Series: | Beilstein Journal of Organic Chemistry |
Subjects: | |
Online Access: | https://doi.org/10.3762/bjoc.8.199 |