Structure of the {U13} polyoxo cluster U13O8Clx(MeO)38–x (x = 2.3, MeO = methoxide)

Structure of the {U13} polyoxo cluster U13O8Clx(MeO)38–x (x = 2.3, MeO = methoxide)

The structure of a new type of polyoxo cluster complex that contains thirteen uranium atoms, {U13}, is reported. The complex crystallized from methanol containing tetravalent uranium (UIV) with a basic organic ligand, and was characterized as dichloridooctacosa-μ2-methanolato-octakis(methanolato)oct...

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Bibliographic Details
Main Authors: Sebastian Fichter, Thomas Radoske, Atsushi Ikeda-Ohno
Format: Article
Language:English
Published: International Union of Crystallography 2021-08-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
polyoxo cluster
f-block elements
actinides
uranium
tetravalent
crystal structure
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989021007623

Internet

http://scripts.iucr.org/cgi-bin/paper?S2056989021007623

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