Structural Basis of CO2 Adsorption in a Flexible Metal-Organic Framework Material

Structural Basis of CO2 Adsorption in a Flexible Metal-Organic Framework Material

This paper reports on the structural basis of CO2 adsorption in a representative model of flexible metal-organic framework (MOF) material, Ni(1,2-bis(4-pyridyl)ethylene)[Ni(CN)4] (NiBpene or PICNIC-60). NiBpene exhibits a CO2 sorption isotherm with characteristic hysteresis and features on the desor...

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Bibliographic Details
Main Authors: Andrew J. Allen, Winnie Wong-Ng, Eric Cockayne, Jeffrey T. Culp, Christopher Matranga
Format: Article
Language:English
Published: MDPI AG 2019-03-01
Series:Nanomaterials
Subjects:
flexible metal-organic frameworks
gate-opening effects
dual gas flow sorption
supercritical CO2 adsorption
small-angle X-ray scattering
small-angle neutron scattering
X-ray diffraction
neutron diffraction
in situ operando studies
density functional theory
Online Access:http://www.mdpi.com/2079-4991/9/3/354

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http://www.mdpi.com/2079-4991/9/3/354

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