First cobalt complexes with methyl pyruvate semi/thiosemicarbazone - synthesis, physico-chemical and structural characterization

First cobalt complexes with methyl pyruvate semi/thiosemicarbazone - synthesis, physico-chemical and structural characterization

In the reaction of acetone solutions of CoX2∙nH2O (X = Cl, Br) with methyl pyruvate semi/thiosemicarbazone (Hmps, Hmpt) the first Co(II) complexes with these ligands, i.e., [Co(Hmps)(H2O)X2] (X = Cl (1), Br (2)), [Co(Hmpt)2][CoCl4]∙2H2О (3) and [Co(Hmpt)2]Br2∙Me2CO (4) were obtained. Complexes 1 and...

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Bibliographic Details
Main Authors: Rodić Marko V., Miškov-Pajić Vukoslava, Leovac Vukadin M., Radanović Mirjana M., Vojinović-Ješić Ljiljana S., Belošević Svetlana K., Jaćimović Željko K., Živković-Radovanović Vukosava
Format: Article
Language:English
Published: Serbian Chemical Society 2020-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
cobalt complexes
hydrazones
single crystal x-ray analysis
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2020/0352-51392000010R.pdf

Internet

http://www.doiserbia.nb.rs/img/doi/0352-5139/2020/0352-51392000010R.pdf

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