Kinetics and Mechanistic Study of the Ruthenium(III) Catalysed Oxidative Decarboxylation of L-Proline by Alkaline Heptavalent Manganese (Stopped flow technique)

The kinetics of ruthenium(III) catalysed oxidation of L-Proline by permanganate in alkaline medium at a constant ionic strength has been studied spectrophotometrically using a rapid kinetic accessory. The reaction between permanganate and L-Proline in alkaline medium exhibits 2:1 stoichiometry (KMnO...

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Bibliographic Details
Main Authors: R. S. Shettar, M. I. Hiremath, S. T. Nandibewoor
Format: Article
Language:English
Published: Hindawi Limited 2005-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2005/369650