Grunwald-Winstein Analysis - Isopropyl Chloroformate Solvolysis Revisited

Grunwald-Winstein Analysis - Isopropyl Chloroformate Solvolysis Revisited

Specific rates of solvolysis at 25 °C for isopropyl chloroformate (1) in 24 solvents of widely varying nucleophilicity and ionizing power, plus literature values for studies in water and formic acid, are reported. Previously published solvolytic rate constants at 40.0 °C are supplemented with two ad...

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Bibliographic Details
Main Authors: Dennis N. Kevill, Jin Burm Kyong, Kevin J. Erdman, Darneisha N. Reed, Malcolm J. D’Souza
Format: Article
Language:English
Published: MDPI AG 2009-03-01
Series:International Journal of Molecular Sciences
Subjects:
Solvolysis
solvolysis-decomposition
nucleophilicity
ionizing power
isopropyl chloroformate
chloroformates
Grunwald-Winstein Equation
Linear Free Energy Relationships
Online Access:http://www.mdpi.com/1422-0067/10/3/862/

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http://www.mdpi.com/1422-0067/10/3/862/

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