Lithium Complexes Derived of Benzylphosphines: Synthesis, Characterization and Evaluation in the ROP of rac-Lactide and ε-Caprolactone

Lithium Complexes Derived of Benzylphosphines: Synthesis, Characterization and Evaluation in the ROP of rac-Lactide and ε-Caprolactone

A series of lithium complexes ([Ph2P(o-C6H4-CH2Li·TMEDA)] (1-Li), [PhP(o-C6H4-CH3)(o-C6H4-CH2Li·TMEDA)] (2-Li), [PhP(o-C6H4-CH2Li·TMEDA)2] (2-Li2) and [P(o-C6H4-CH2Li·TMEDA)3] (3-Li3)) was prepared from mono-, di- and tri-benzylphosphines and varying amounts of nBuLi and was characterized extensivel...

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Bibliographic Details
Main Authors: Ernesto Rufino-Felipe, Miguel-Ángel Muñoz-Hernández, Virginia Montiel-Palma
Format: Article
Language:English
Published: MDPI AG 2017-12-01
Series:Molecules
Subjects:
organolithium
lithium organophosphines
DFT computations
ROP
rac-LA polymerization
ε-caprolactone polymerization
Online Access:https://www.mdpi.com/1420-3049/23/1/82

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https://www.mdpi.com/1420-3049/23/1/82

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