Synthesis and Characterization of a Heterometallic Extended Architecture Based on a Manganese(II)-Substituted Sandwich-Type Polyoxotungstate

Synthesis and Characterization of a Heterometallic Extended Architecture Based on a Manganese(II)-Substituted Sandwich-Type Polyoxotungstate

The reaction of [α-P2W15O56]12− with MnII and DyIII in an aqueous basic solution led to the isolation of an all inorganic heterometallic aggregate Na10(OH2)42[{Dy(H2O)6}2Mn4P4W30O112(H2O)2]·17H2O (Dy2Mn4-P2W15). Single-crystal X-ray diffraction revealed that Dy2Mn4-P2W15 crystallizes in the triclini...

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Bibliographic Details
Main Authors: Masooma Ibrahim, Eufemio Moreno-Pineda, Thomas Bergfeldt, Christopher E. Anson, Annie K. Powell
Format: Article
Language:English
Published: MDPI AG 2018-01-01
Series:Materials
Subjects:
heterometallic
3d-4f polyoxometalate
molecular magnetism
luminescence
pomif
extended frameworks
trilacunary
wells-dawson polyanion
sandwich-type
Online Access:http://www.mdpi.com/1996-1944/11/1/155

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http://www.mdpi.com/1996-1944/11/1/155

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