Bi(OTf)3 and SiO2-Bi(OTf)3 as Effective Catalysts for the Ferrier Rearrangement#

Bi(OTf)3 and SiO2-Bi(OTf)3 are found to effectively catalyze the Ferrierrearrangement of tri-O-acetyl glycals with different alcohols providing an effective routeto 2,3-unsaturated O-glycosides with good anomeric selectivity and good to excellentyields after short reaction times.

Bibliographic Details
Main Authors: Y. Vankar, A. Khare, J. Babu
Format: Article
Language:English
Published: MDPI AG 2005-08-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/10/8/884/