Cationic Site-Preference in the Yb14-xCaxAlSb11 (4.81 ≤ x ≤ 10.57) Series: Theoretical and Experimental Studies

Cationic Site-Preference in the Yb14-xCaxAlSb11 (4.81 ≤ x ≤ 10.57) Series: Theoretical and Experimental Studies

Four quaternary Zintl phases with mixed-cations in the Yb14-xCaxAlSb11 (4.81 ≤ x ≤ 10.57) series have been synthesized by using the arc-melting and the Sn metal-flux reaction methods, and the isotypic crystal structures of the title compounds have been characterized by both powder and single-crystal...

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Bibliographic Details
Main Authors: Gnu Nam, Eunyoung Jang, Hongil Jo, Mi-Kyung Han, Sung-Jin Kim, Kang Min Ok, Tae-Soo You
Format: Article
Language:English
Published: MDPI AG 2016-07-01
Series:Materials
Subjects:
Zintl phases
single-crystal X-ray diffraction
site preference
electronic structure
mixed cations
Online Access:http://www.mdpi.com/1996-1944/9/7/553

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http://www.mdpi.com/1996-1944/9/7/553

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