Synthesis of chiral N-phosphoryl aziridines through enantioselective aziridination of alkenes with phosphoryl azide via Co(II)-based metalloradical catalysis

Synthesis of chiral N-phosphoryl aziridines through enantioselective aziridination of alkenes with phosphoryl azide via Co(II)-based metalloradical catalysis

The Co(II) complex of a new D2-symmetric chiral porphyrin 3,5-DiMes-QingPhyrin, [Co(P6)], can catalyze asymmetric aziridination of alkenes with bis(2,2,2-trichloroethyl)phosphoryl azide (TcepN3) as a nitrene source. This new Co(II)-based metalloradical aziridination is suitable for different aromati...

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Bibliographic Details
Main Authors: Jingran Tao, Li-Mei Jin, X. Peter Zhang
Format: Article
Language:English
Published: Beilstein-Institut 2014-06-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
asymmetric aziridination
aziridine
chiral porphyrin
cobalt complex
metalloradical catalysis
organophosphorus
phosphoryl azide
Online Access:https://doi.org/10.3762/bjoc.10.129

Internet

https://doi.org/10.3762/bjoc.10.129

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