Crystal structure of tetrakis[μ2-2-(dimethylamino)ethanolato-κ3N,O:O]di-μ3-hydroxido-dithiocyanato-κ2N-dichromium(III)dilead(II) dithiocyanate acetonitrile monosolvate

Crystal structure of tetrakis[μ2-2-(dimethylamino)ethanolato-κ3N,O:O]di-μ3-hydroxido-dithiocyanato-κ2N-dichromium(III)dilead(II) dithiocyanate acetonitrile monosolvate

The tetranuclear complex cation of the title compound, [Cr2Pb2(NCS)2(OH)2(C4H10NO)4](SCN)2·CH3CN, lies on an inversion centre. The main structural feature of the cation is a distorted seco-norcubane Pb2Cr2O6 cage with a central four-membered Cr2O2 ring. The CrIII ion is coordinated in a distorted oc...

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Bibliographic Details
Main Authors: Julia A. Rusanova, Valentyna V. Semenaka, Irina V. Omelchenko
Format: Article
Language:English
Published: International Union of Crystallography 2016-04-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
N,N′-dimethylethanolamine
heterometal PbII/CrIII complex
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989016003996

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http://scripts.iucr.org/cgi-bin/paper?S2056989016003996

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