Disorder of the dimeric TCNQ–TCNQ unit in the crystal structure of [Ni(bpy)3]2(TCNQ–TCNQ)(TCNQ)2·6H2O (TCNQ is 7,7,8,8-tetracyanoquinodimethane)

Disorder of the dimeric TCNQ–TCNQ unit in the crystal structure of [Ni(bpy)3]2(TCNQ–TCNQ)(TCNQ)2·6H2O (TCNQ is 7,7,8,8-tetracyanoquinodimethane)

Crystallization from an aqueous methanol system composed of Ni(NO3)2, 2,2′-bipyridine (bpy) and LiTCNQ (TCNQ is 7,7,8,8-tetracyanoquinodimethane) in a 1:3:2 molar ratio yielded single crystals of bis[tris(2,2′-bipyridine-κ2N,N′)nickel(II)] bis(7,7,8,8-tetracyanoquinodimethane radical anion) bi[7,7,8...

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Bibliographic Details
Main Authors: Juraj Černák, Juraj Kuchár, Michal Hegedüs
Format: Article
Language:English
Published: International Union of Crystallography 2017-01-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
nickel
2,2′-bipyridine
σ-dimerized TCNQ–TCNQ dianion
disorder
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989016019162

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http://scripts.iucr.org/cgi-bin/paper?S2056989016019162

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