Metal-free synthesis of biarenes via photoextrusion in di(tri)aryl phosphates

A metal-free route for the synthesis of biarenes has been developed. The approach is based on the photoextrusion of a phosphate moiety occurring upon irradiation of biaryl- and triaryl phosphates. The reaction involves an exciplex as the intermediate and it is especially suitable for the preparation...

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Bibliographic Details
Main Authors: Hisham Qrareya, Lorenzo Meazza, Stefano Protti, Maurizio Fagnoni
Format: Article
Language:English
Published: Beilstein-Institut 2020-12-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.16.250