Crystal structure of {6,6′-dibenzoyl-4,4′-di-tert-butyl-2,2′-[(ethane-1,2-diyl)dinitrilobis(phenylmethanylylidene)]diphenolato-κ4O1,N,N′,O1′}nickel(II)

Crystal structure of {6,6′-dibenzoyl-4,4′-di-tert-butyl-2,2′-[(ethane-1,2-diyl)dinitrilobis(phenylmethanylylidene)]diphenolato-κ4O1,N,N′,O1′}nickel(II)

The mononuclear title complex, [Ni(C50H46N2O4)], crystallizes in the triclinic space group P-1, with two molecules in the asymmetric unit (Z′ = 2). Each NiII atom has a slightly distorted square-planar geometry [ω = 3.91 (5)° and 2.04 (7)°] defined by the two phenolate O and two imine N atoms of the...

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Bibliographic Details
Main Authors: Abhishek K. Gupta, Ray J. Butcher, Anjan Sil
Format: Article
Language:English
Published: International Union of Crystallography 2015-12-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
synthesis
NiII complex
N2O2 Schiff base
C—H...O hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015021052

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http://scripts.iucr.org/cgi-bin/paper?S2056989015021052

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