Synthesis of Highly Functionalised Enantiopure Bicyclo[3.2.1]- octane Systems from Carvone

Synthesis of Highly Functionalised Enantiopure Bicyclo[3.2.1]- octane Systems from Carvone

The commercially available monoterpene carvone has been efficiently convertedinto the tricyclo[3.2.1.02.7]octane and bicyclo[3.2.1]octane systems characteristic of somebiologically active compounds. The sequence used for this transformation involves as keyfeatures an intramolecular Diels-Alder react...

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Bibliographic Details
Main Authors: Noelia Vera, Ismael Navarro, Ignacio de Alfonso, Ana C. Cuñat, Consuelo Agulló, Antonio Abad
Format: Article
Language:English
Published: MDPI AG 2004-04-01
Series:Molecules
Subjects:
Carvone
Diels-Alder reaction
cyclopropane cleavage
5-vinyl-1
3- cyclohexadiene
samarium diiodide
bicyclo[3.2.1]octane
tricyclo[3.2.1.02.7]octane
Online Access:http://www.mdpi.com/1420-3049/9/5/287/

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http://www.mdpi.com/1420-3049/9/5/287/

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